WebMay 21, 1998 · 8. Typical Procedure for thiolester 2a: To a round flask was added 1-(methylthio)-2-phenyletyne 1a (0.148 g; 1 mmol), 5 mL of dichloromethane, p-TsOH (0.19 … WebQuestion: Predict the major products for the following reactions. NH CH3NH2 TsOH TsOH OH A) NCH3 B) OH NHCH3 HO C) NCH3 N D) H3CHN NHCH3 -N E) NHCH3 НО. -N Predict …
p-Toluenesulfonic acid ACS reagent, = 98.5 6192-52-5
WebPh HO 3P=CH2 BH3-THF; H2O2, NaOH CO2H HO HO 3 eq LDA; 1 eq t-BuMe2SiCl CO2H HO Me2t-BuSiO (6) See also P. V. Ramachandran J. Org. Chem. 2001, 66, 2512. ... H2O2 Ph OSiEt3 HO HO2C 1) TBAF 2) cat TsOH Ph O HO O (8) Ph NHMe OH NEt3, THF Ph O N Ph OH Ph O Cl 2 eq LDA, LiCl; BnOCH2Cl Ph O R2N OBn LiAlH(OEt)3 OHC Ph OBn OSiMe2t-Bu cat … Web(Ph)3P Butyllithium will react with the ketone, and the reagent will react with itself! Me O Br MeOH, H+ Me Br MeOOMe Me (Ph)3P MeOOMe A stable reagent O Me MeOOMe Me O H2O, H+ Acetals as Carbonyl Protecting Groups. OH Me Me Me Me MeOOH a hemiacetal O Me Me O Me Me H MeO H H+ MeOH MeOH (usually unstable for ketones, csi ny misconception
Trimethyl orthoformate - Wikipedia
Webph o ( n) ho ho ho oh oh 22. c11h23 c6h13 tsoh ch2cl2 co2h cl cl cl o d. naoh a. no2 cl no2 b. cl c. ch3 d. no2 12. 下列化合物的四个羟基中与重氮甲烷反应活性最低的是( ) a oh oh b c ho o oh d 13. 四氢呋喃与碘化钾、多聚磷酸共热反应得到的产物是( ) i a. o i b. o i i 14. 适用于下列反应的 ... WebThe composite, 1@graphene evolves H2 gas from p-toluene sulfonic acid (TsOH) in a mixture of H2O and CH3CN under ambient conditions with a significant turnover number of 3200. 1@graphene electro-catalyzes H2 evolution at Ep, −1.2 V with remarkable throughput, catalytic efficiency and stability in only H2O or in only CH3CN. WebMethod A: DCC/DMAP/TsOH in CH2Cl2 Method B: BuLi in THF N° R Method % 12 Ph A 98 B90 13 Bn A 85 B81 Bn = Ph-CH2 Method A: Z = OH; Method B: Z = Cl RCOZ OH HO O O R R O Scheme 5. Synthesis of unsaturated diesters 12 and 13. 4 R = H, Me R2 COZ R1 R 14 - 21 Method A or Method B 3 N° R R1 R2 Method A Method B (%) (%) 14 H Ph H 60 91 15a … csi ny obsession